FSMO Roles
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Schema Master: The schema master domain controller controls all updates and modifications to the schema. To update the schema of a forest, you must have access to the schema master. There can be only one schema master in the whole forest.Domain naming master: The domain naming master domain controller controls the addition or removal of domains in the forest. There can be only one domain naming master in the whole forest.Infrastructure Master: The infrastructure is responsible for updating references from objects in its domain to objects in other domains. At any one time, there can be only one domain controller acting as the infrastructure master in each domain.Relative ID (RID) Master: The RID master is responsible for processing RID pool requests from all domain controllers in a particular domain. At any one time, there can be only one domain controller acting as the RID master in the domain.PDC Emulator: The PDC emulator is a domain controller that advertises itself as the primary domain controller (PDC) to workstations, member servers, and domain controllers that are running earlier versions of Windows.
To change the Roles See the Link : http://support.microsoft.com/kb/324801
